Keracunan K-OTHRINE (Deltamethrin)

https://sds.rentokil-initial.com/sds/files/ID-Rentokil-Aqua_K_Othrine_EW20-EN-SDSxxxx_03_REACH.pdf

IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY/UNDERTAKING

Product information Trade name : AQUA K-OTHRINE EW20 12X1L BOT ID Product code : (UVP) 06477399 Usage : Insecticide Company : Bayer CropScience AG Alfred-Nobel-Straße 50 40789 Monh

HAZARDS IDENTIFICATION

Risk advice to man and the environment Harmful if swallowed. Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Harmful: may cause lung damage if swallowed. Repeated exposure may cause skin dryness or cracking.

COMPOSITION/INFORMATION ON INGREDIENTS

Chemical nature Emulsion, oil in water (EW) : Deltamethrin 20 g/l

FIRST AID MEASURES

General advice Remove contaminated clothing immediately and dispose of safely. Inhalation Move to fresh air. Keep patient warm and at rest. If symptoms persist, call a physician.

Skin contact In case of skin contact, immediately wash with plenty of water and soap for at least 15 minutes. After skin contact: Apply Vitamin E cream or a simple body milk. If symptoms persist, call a physician. Eye contact Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Remove contact lenses, if present, after the first 5 minutes, then continue rinsing eye. Get medical attention if irritation develops and persists. Ingestion Rinse out mouth and give water in small sips to drink. Do NOT induce vomiting. Risk of product entering the lungs on vomiting after ingestion. If swallowed, seek medical advice immediately and show this container or label. Notes to Physician Symptoms Local:, skin and eye paraesthesia which may be severe, Usually transient with resolution within 24 hours., eye and mucous membrane irritation, cough Symptoms Systemic:, discomfort in the chest, tachycardia, hypotension, nausea, Abdominal pain, Diarrhoea, Vomiting, dizziness, blurred vision, headache, anorexia, somnolence, Coma, Convulsions, Tremors, prostration Risks This product contains a pyrethroid. Must NOT be confused with organophosphorus compounds! Treatment Local treatment: Initial treatment: symptomatic. Treatment Systemic treatment: Endotracheal intubation and gastric lavage, followed by administration of charcoal. Monitoring of respiratory and cardiac functions. ECG - monitoring (Electrocardiogram). Check for pulmonary oedema in event of inhalation. Keep airway clear, administer artificial respiration if necessary. Against convulsions: give diazepam. For adults 5-10 mg intravenously as necessary until fully sedated; for children 2.5 mg i.v. There is no specific antidote. Contraindication: atropine. Contraindication: derivatives of adrenaline. Spontaneous recovery.

ACCIDENTAL RELEASE MEASURES

Personal Precautions Keep people away from and upwind of spill/leak. Avoid contact with spilled product or contaminated surfaces. When dealing with a spillage do not eat, drink or smoke. Environmental Precautions Do not allow to get into surface water, drains and ground water. Methods for Cleaning Up Keep in suitable, closed containers for disposal. Clean floors and contaminated objects with plenty of water. Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal binder).

HANDLING AND STORAGE

Handling Advice on safe handling No specific precautions required when handling unopened packs/containers; follow relevant manual handling advice. Use only in area provided with appropriate exhaust ventilation. Advice on protection against fire and explosion Keep away from heat and sources of ignition. Vapours may form explosive mixture with air.

Respiratory Protection

No personal respiratory protective equipment normally required. Respiratory protection should only be used to control residual risk of short duration activities, when all reasonably practicable steps have been taken to reduce exposure at source e.g. containment and/or local extract ventilation. Always follow respirator manufacturer's instructions regarding wearing and maintenance.

Hand Protection

Wear CE Marked (or equivalent) nitrile rubber gloves (minimum thickness 0,40 mm). Wash when contaminated. Dispose of when contaminated inside, when perforated or when contamination outside cannot be removed. Wash hands always before eating, drinking, smoking or using the toilet.

Eye Protection

Wear goggles conforming to EN166 (Field of Use 5 or equivalent).

Skin and body protection

Wear standard coverall and type 6 suit. Wear two layers of clothing wherever possible. Polyester/cotton or cotton overalls should be worn under chemical protection suit and should be professionally laundered frequently.

Hygiene measures

When using, do not eat, drink or smoke. Remove soiled clothing immediately and clean thoroughly before using again. Wash hands immediately after work, if necessary take a shower.

PHYSICAL AND CHEMICAL PROPERTIES

Appearance Form suspension, opaque Colour white Odour strong, characteristic

STABILITY AND REACTIVITY

Conditions to Avoid Extremes of temperature and direct sunlight. Hazardous Reactions No hazardous reactions when stored and handled according to prescribed instructions. Stable under recommended storage conditions.

TOXICOLOGICAL INFORMATION

Acute Oral Toxicity LD50 (rat) 2.416 mg/kg Acute Inhalation Toxicity LC50 (rat) > 5,80 mg/l Exposure time: 4 h Highest attainable concentration. When inhaled in high concentration, the solvent vapours cause a narcotic effect.

Acute Dermal Toxicity LD50 (rat) > 5.000 mg/kg

Skin Irritation Slight irritant effect - does not require labelling. (rabbit)

Eye Irritation Slight irritant effect - does not require labelling. (rabbit)

Sensitization Non-sensitizing. (guinea pig) OECD Test Guideline 406, Buehler test

Further information Cutaneous sensations may occur, such as burning or stinging on the face and mucosae. However, these sensations cause no lesions and are of a transitory nature (max. 24 hours).

ECOLOGICAL INFORMATION

Elimination information (persistence and degradability)

Bioaccumulation → Bluegill sunfish Bioconcentration factor (BCF): 1.400 The value mentioned relates to the active ingredient deltamethrin.

Ecotoxicity effects

Toxicity to Fish → LC50 (Cyprinus carpio (Carp)) 0,0539 mg/l Exposure time: 96 h

Toxicity to daphnia → EC50 (Water flea (Daphnia magna)) 0,00056 mg/l Exposure time: 48 h The value mentioned relates to the active ingredient deltamethrin.

Toxicity to algae → EC50 (Algae) > 9,1 mg/l Exposure time: 72 h The value mentioned relates to the active ingredient deltamethrin.

Bird toxicity → LD50: > 5,000 mg/kg duck LD50: > 10,000 mg/kg quail

Bee toxicity → Deltamethrin found to be highly toxic in lab studies but considered less toxic under natural conditions

Environmental fate,

Deltamethrin is not persistent in the environment. It is destroyed by soil persistence and degradation micro-organisms and does not leave residues in the environment or build up in the food chain..

DISPOSAL CONSIDERATIONS

Product→ In accordance with current regulations and, if necessary, after consultation with the site operator and/or with the responsible authority, the product may be taken to a waste disposal site or incineration plant.

Contaminated packaging → Triple rinse containers. Do not re-use empty containers. Not completely emptied packagings should be disposed of as hazardous waste.

Waste key for the unused product → 020108 agrochemical waste containing dangerous substances

REGULATORY INFORMATION

Classification and labelling in accordance with the EC Directive on dangerous preparations 1999/45/EC as amended.

Classification: → Hazard warning labelling compulsory

Hazardous components which must be listed on the label:

• Deltamethrin

• Solvent Naphtha (petroleum), heavy aromatic

Symbol(s) →

Xn Harmful

N Dangerous for the environment

R-phrase(s)

 R22 Harmful if swallowed.

R50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.

R65 Harmful: may cause lung damage if swallowed. R66 Repeated exposure may cause skin dryness or cracking.

S-phrase(s)

S35 This material and its container must be disposed of in a safe way.

S57 Use appropriate container to avoid environmental contamination.

S62 If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label.

Exceptional labelling  →To avoid risks to man and the environment, comply with the instructions for use.

Further information →WHO-classification: III (Slightly hazardous)

R23/25 → Toxic by inhalation and if swallowed.

R50/53 → Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.

R51/53 → Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.

R65 → Harmful: may cause lung damage if swallowed.

R66 → Repeated exposure may cause skin dryness or cracking.

.